Inorganic/Organic Mesostructures with Complex Architectures: Precipitation of Calcium Phosphate in the Presence of Double-Hydrophilic Block Copolymers

Markus Antonietti, Michael Breulmann, Christine G. Göltner, Helmut Cölfen, Kim K. W. Wong, Dominic Walsh, Stephen Mann

Chemistry - A European Journal · 1998 · 217 citations · 0 references

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Abstract

Hybrid colloids with new and unusual morphologies (see figure) are formed by precipitation of calcium phosphates in the presence of hydrophobically modified double-hydrophilic block copolymer micelles. The use of interactive polymer templates broadens the toolbox of chemistry required for the construction of complex structures on the nanometer and mesoscopic scale.