Concepedia

Stabilization of Mesoporous Molecular Sieves by Trimethylsilylation

Keiko A. Koyano, Takashi Tatsumi, Yoshinori Tanaka, Shinichi Nakata

The Journal of Physical Chemistry B · 1997 · 291 citations · 17 references

DOI

Concepts

Abstract

The stability of Si-MCM-48 to moisture and compression can be improved by trimethylsilylation, as a result of the increase in hydrophobicity. Moreover, the stability is retained after calcination, although the calcined material is no longer hydrophobic. This stabilizing effect was also observed for Si-MCM-41 and Ti-MCM-41.

References

17

A new family of mesoporous molecular sieves prepared with liquid crystal templates

Jeffrey S. Beck, J.C. Vartuli, Wiesław J. Roth et al. · Journal of the American Chemical Society · 1992 · 10.9K citations

, , +10

Titanium-containing mesoporous molecular sieves for catalytic oxidation of aromatic compounds

Peter T. Tanev, Malama Chibwe, Thomas J. Pinnavaia · Nature · 1994 · 1.8K citations

, , +16

Synthesis of highly ordered mesoporous materials from a layered polysilicate

Shinji Inagaki, Y. Fukushima, Kazuyuki Kuroda · Journal of the Chemical Society Chemical Communications · 1993 · 1.2K citations

, , +13

Studies on mesoporous materials

Cong-Yan Chen, Hong‐Xin Li, Mark E. Davis · Microporous Materials · 1993 · 937 citations

, , +11

Disordered Molecular Sieve with Branched Mesoporous Channel Network

Ryong Ryoo, Jong‐Man Kim, C. H. Ko et al. · The Journal of Physical Chemistry · 1996 · 456 citations

, , +15