Bulletin of the Chemical Society of Japan · 1977 · 48 citations · 8 references
Natural SciencesChemistryInorganic ChemistryOrganic ChemistryOrganometallic ChemistryCoordination ChemistryStructural Elucidation
Abstract 2-Pyridylferrocene reacts with lithium tetrachloropalladate(II) in the presence of sodium acetate to give an ortho-palladated binuclear complex (4). The σ-bonded structure of 4 was confirmed by studies of the IR and NMR spectra and of the reactions of 4 with thallium (I) acetylacetonate and lithium aluminum deuteride. The reactions of 4 with carbon monoxide, butyllithium, and bromine were also examined.
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