Utilisation de la méthode de Wittig pour la synthèse de vinyl-2 aziridines N-substituées

Abstract

Several 2-vinylaziridines were prepared by treating N-substituted 2-acylaziridines with phosphoranes. The stereochemistry of the ring and the double bond of the products was established from a study of their nmr spectra. The geometry of the starting material 2-acylaziridine is conserved in the 2-vinylaziridine formed. [Journal translation]