New Journal of Chemistry · 2004 · 84 citations · 13 references
EngineeringMembrane CharacterizationDiffusion Permeability CoefficientIon ProcessMembrane FusionChemical EngineeringMembrane TransportIon-exchange Membrane CharacterisationProton-exchange MembraneTransport PhenomenaAnalytical ChemistryNew ProcedureBiophysicsIon ExchangeBiochemistryIon-exchange MembranesMembrane PermeationElectrochemistryMembrane BiophysicsMedicine
A new procedure for the characterisation of the transport properties of ion-exchange membranes (IEM) is proposed. Only three characteristics have to be measured: the electrical conductivity, the diffusion permeability coefficient and the apparent transport number. To complete the set of parameters, two complementary characteristics, the true counter-ion transport number and the water transport number, are calculated from the Scatchard equation and from a novel equation deduced earlier. The possibilities to reduce the number of initial measurements are discussed in three cases.
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Donald G. Miller · The Journal of Physical Chemistry · 1966 · 268 citations
George Scatchard · Journal of the American Chemical Society · 1953 · 131 citations