Angewandte Chemie International Edition in English · 1964 · 106 citations · 27 references
Natural SciencesChemistryChemical KineticsInorganic ChemistryPhysical ChemistryAddition ReactionsNucleophile ReactivityNucleophilic ReactivityReversible Reaction KineticsStructure-reactivity RelationshipsThermodynamic Versus Kinetic Control
Abstract The effect of the nature of the coreactants and the reaction conditions on the ability of certain mesomeric cations to react with nucleophilic reagents to form isomeric products has been studied. The structures of the products isolated are determined by competition between a kinetically controlled but reversible reaction and a thermodynamically controlled reaction.
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A. N. Bourns, E Buncel · Annual Review of Physical Chemistry · 1961 · 418 citations
Nathan Kornblum, Robert A. Smiley, Robert K. Blackwood et al. · Journal of the American Chemical Society · 1955 · 292 citations
Neighboring methoxyl participation in solvolytic nucleophilic substitution
S. Winstein, Evan L. Allred, Richard F. Heck et al. · Tetrahedron · 1958 · 107 citations