Concepedia

Improved Hydrogen Storage in the Metal‐Organic Framework Cu<sub>3</sub>(BTC)<sub>2</sub>

Piotr Krawiec, Markus Krämer, Michal Sabo, R. Kunschke, Heidrun Fröde, Stefan Kaskel

Advanced Engineering Materials · 2006 · 189 citations · 24 references

DOI

Concepts

Abstract

A new pressure‐free synthesis method was developed producing the porous material Cu 3 (BTC) 2 (BTC = benzene tricarboxylate) with a very high micropore volume up to 0.62 cm 3 g –1 . The compound is a promising nanoporous solid for adsorptive hydrogen storage under cryogenic conditions with a capacity of 2.18 wt% which is higher than that of IRMOFs and other coordination polymers.

References

24

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A Chemically Functionalizable Nanoporous Material [Cu <sub>3</sub> (TMA) <sub>2</sub> (H <sub>2</sub> O) <sub>3</sub> ] <sub> <i>n</i> </sub>

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Nathaniel L. Rosi, Juergen Eckert, Mohamed Eddaoudi et al. · Science · 2003 · 4.8K citations

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