Concepedia

Palladium-Catalyzed Diarylmethyl C(sp<sup>3</sup>)–C(sp<sup>2</sup>) Bond Formation: A New Coupling Approach toward Triarylmethanes

Ying Xia, Fangdong Hu, Zhenxing Liu, Peiyuan Qu, Rui Ge, Chen Ma, Yan Zhang, Jianbo Wang

Organic Letters · 2013 · 90 citations · 45 references

DOI

Abstract

Palladium-catalyzed reductive coupling reactions between N-tosylhydrazones and aryl halides lead to the formation of C(sp(3))-C(sp(2)) bonds. This approach provides a general route for the synthesis of triarylmethanes.

References

45

Palladium‐Catalyzed Cross‐Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

Carin C. C. Johansson Seechurn, Matthew O. Kitching, Thomas J. Colacot et al. · Angewandte Chemie International Edition · 2012 · 2.9K citations · Full text

, , +13

Palladium‐Catalyzed Cross‐Coupling Reactions in Total Synthesis

K. C. Nicolaou, Paul G. Bulger, David Šarlah · Angewandte Chemie International Edition · 2005 · 2.7K citations

, , +9

Cross‐Coupling Reactions Of Organoboranes: An Easy Way To Construct CC Bonds (Nobel Lecture)

Akira Suzuki · Angewandte Chemie International Edition · 2011 · 2K citations

Diazo Compounds and <i>N</i>-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions

Qing Xiao, Yan Zhang, Jianbo Wang · Accounts of Chemical Research · 2012 · 960 citations

, , +12

Tosylhydrazones: New Uses for Classic Reagents in Palladium‐Catalyzed Cross‐Coupling and Metal‐Free Reactions

José Barluenga, Carlos Valdés · Angewandte Chemie International Edition · 2011 · 654 citations · Full text