Enantioselective synthesis of cis-7-methoxy-calamenene via Claisen rearrangement of an enzymatically resolved allyl alcohol

Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones

Yoshiaki Takaya, Masamichi Ogasawara, Tamio Hayashi et al. · Journal of the American Chemical Society · 1998 · 682 citations

Asymmetric Catalysis, Chemical Engineering, Cross-coupling Reaction +13

Simple stereoselective version of the Claisen rearrangement leading to trans-trisubstituted olefinic bonds. Synthesis of squalene

William S. Johnson, Lucius Werthemann, William R. Bartlett et al. · Journal of the American Chemical Society · 1970 · 629 citations

Engineering, Alkene Metathesis, Claisen Rearrangement +11

Regioselective, Diastereoselective, and Enantioselective Lithiation−Substitution Sequences:  Reaction Pathways and Synthetic Applications

Peter Beak, Amit Basu, Donald J. Gallagher et al. · Accounts of Chemical Research · 1996 · 578 citations

Molecular Sciences, Engineering, Chemical Analysis +13

Pseudoephedrine as a Practical Chiral Auxiliary for the Synthesis of Highly Enantiomerically Enriched Carboxylic Acids, Alcohols, Aldehydes, and Ketones

Andrew G. Myers, Bryant H. Yang, Hou Chen et al. · Journal of the American Chemical Society · 1997 · 560 citations

Tertiary Amides, Natural Sciences, Diversity-oriented Synthesis +10

The Enantioselective Organocatalytic 1,4-Addition of Electron-Rich Benzenes to α,β-Unsaturated Aldehydes

Nick A. Paras, David W. C. MacMillan · Journal of the American Chemical Society · 2002 · 339 citations

Medicinal Chemistry, Chemical Engineering, Iminium Catalysis +14