Concepedia

Niobium and vanadium iminophosphinimide complexes

Justin K. Brask, Michael G. Fickes, Preeyanuch Sangtrirutnugul, V. Dura-Vila, Aaron L. Odom, Christopher C. Cummins

Chemical Communications · 2001 · 34 citations · 7 references

DOI

Concepts

Abstract

The iminophosphinimide complexes [Ar(R)N]3M(NPNBut) (M = V, Nb) were prepared from the corresponding anionic nitride species ([Ar(R)N]3M identical to NNa)2 by way of a four-step synthetic strategy.

References

7

Bicyclic and tricyclic bis(amido)cyclodiphosph(III)azane compounds of main group elements

Lothar Stahl · Coordination Chemistry Reviews · 2000 · 179 citations

, , +12

Reductive Cleavage of Dinitrogen by a Vanadium Diamidoamine Complex:  the Molecular Structures of [V(Me<sub>3</sub>SiN{CH<sub>2</sub>CH<sub>2</sub>NSiMe<sub>3</sub>}<sub>2</sub>)(μ-N)]<sub>2</sub> and K[V(Me<sub>3</sub>SiN{CH<sub>2</sub>CH<sub>2</sub>NSiMe<sub>3</sub>}<sub>2</sub>)(μ-N)]<sub>2</sub>

G.K.B. Clentsmith, V.M. Bates, Peter B. Hitchcock et al. · Journal of the American Chemical Society · 1999 · 171 citations

, , +4

Isolation and Structural Characterization of the Terminal Mesityl Azide Complex V(N3Mes)(I)(NRArF)2 and Its Conversion to a Vanadium(V) Imido Complex

Michael G. Fickes, William M. Davis, Christopher C. Cummins · Journal of the American Chemical Society · 1995 · 138 citations

, , +11

Synthesis of Terminal Vanadium(V) Imido, Oxo, Sulfido, Selenido, and Tellurido Complexes by Imido Group or Chalcogenide Atom Transfer to Trigonal Monopyramidal V[N3N] (N3N = [(Me3SiNCH2CH2)3N]3-)

Christopher C. Cummins, Richard R. Schrock, William M. Davis · Inorganic Chemistry · 1994 · 131 citations

, , +7

Synthesis and Structure of a Terminal Metal Azide Complex: An Isolated Intermediate in the Formation of Imidometal Complexes from Organic Azides

Grant Proulx, Robert G. Bergman · Journal of the American Chemical Society · 1995 · 100 citations

, , +10