Concepedia

A diruthenium(II) complex containing an unprecedented bridging S,O-bidentate dimethyl sulfoxide ligand

Tomoaki Tanase, T. Aiko, Yasuhiro Yamamoto

Chemical Communications · 1996 · 25 citations · 3 references

DOI

Concepts

Abstract

The diruthenium(II) complex [Ru2(µ-Cl)(µ-H)(µ-Me2SO)-Cl2(Me2SO)4]·2CH2Cl2 is prepared from [RuCl2(Me2SO)4] in methanol in the presence of Na2(xdk)[H2xdk =m-xylenediamine bis(Kemp's triacid imide)] and characterized by X-ray crystallography which reveals an unprecedented S,O-bidentate bridging Me2SO ligand.

References

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Synthesis, molecular structure, and chemical behavior of hydrogen trans-bis(dimethyl sulfoxide)tetrachlororuthenate(III) and mer-trichlorotris(dimethyl sulfoxide)ruthenium(III): the first fully characterized chloride-dimethyl sulfoxide-ruthenium(III) complexes

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Dinuclear Manganese(II) Complexes with the {Mn2(.mu.-carboxylato)2}2+ Core and Their Transformation to (.mu.-Oxo)bis(.mu.-carboxylato)dimanganese(III) Complexes

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