Adsorbed carbocations as transition states in heterogeneous acid catalyzed transformations of hydrocarbons

Absolute electronegativity and hardness: application to inorganic chemistry

Ralph G. Pearson · Inorganic Chemistry · 1988 · 3.4K citations

Natural Sciences, Chemistry, Inorganic Chemistry +5

Reactions of propene on zeolite HY catalyst studied by in situ variable temperature solid-state nuclear magnetic resonance spectroscopy

James F. Haw, Benny R. Richardson, Irene Sueko Oshiro et al. · Journal of the American Chemical Society · 1989 · 314 citations

Natural Sciences, Chemical Engineering, Chemistry +12

Monomolecular and bimolecular mechanisms of paraffin cracking: n-butane cracking catalyzed by HZSM-5

H. Krannila · Journal of Catalysis · 1992 · 284 citations

Natural Sciences, Chemical Engineering, Chemistry +8

Super acids. III. Protonation of alkanes and intermediacy of alkanonium ions, pentacoordinated carbon cations of CH5+ type. Hydrogen exchange, protolytic cleavage, hydrogen abstraction; polycondensation of methane, ethane, 2,2-dimethylpropane and 2,2,3,3-tetramethylbutane in FSO3H-SbF5

George A. Olah, Gilles Klopman, Richard H. Schlosberg · Journal of the American Chemical Society · 1969 · 281 citations

Natural Sciences, Chemistry, Catalysis +5

Quantum chemical study of the electronic structure and geometry of surface alkoxy groups as probable active intermediates of heterogeneous acidic catalysts: What are the adsorbed carbenium ions?

V.B. Kazansky · Journal of Catalysis · 1989 · 176 citations

Natural Sciences, Chemical Engineering, Chemistry +17