Publication | Closed Access
Development of Binaphthyl-Based Chiral Dienes for Rhodium(I)-Catalyzed Asymmetric Arylation of <i>N</i>,<i>N</i>-Dimethylsulfamoyl-Protected Aldimines
85
Citations
45
References
2010
Year
Binaphthyl-based Chiral DienesArylboronic AcidsChemical EngineeringN-dimethylsulfamoyl-protected AldiminesEngineeringCross-coupling ReactionAsymmetric ArylationOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
A variety of binaphthyl-based chiral dienes were synthesized and utilized as steering ligands for the enantioselective arylation of N,N-dimethylsulfamoyl-protected aldimines with arylboronic acids, and moderate to good yields and up to 84% ee were achieved.
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