Langmuir · 2002 · 50 citations · 24 references
Natural SciencesChemistryMaterials SciencePhysical ChemistrySupramolecular ChemistrySurface ScienceGelsHydrogelsSolution ChemistrySupramolecular GelsSupramolecular MaterialsSurfactantsAnionic SurfactantsGel PhaseGelation MechanismsPhase Behavior Of Surfactant SystemsSurface Tension MeasurementSurfactant Phase BehaviorSurfactant SystemsX-ray Diffraction Analysis
The 6- O -ascorbic acid alkanoates, ascorbyl-OCO(CH 2 ) n- 2 CH 3 (ASC n ), behave as anionic surfactants in water. At low water content (10% w/v) aqueous dispersions also form coagels at room temperature. These hydrated crystalline phases transform to micellar solutions or gel phases, depending on the length of the hydrophobic chain in the surfactant. The formation and properties of these phases were studied through surface tension, differential scanning calorimetry (DSC), X-ray diffraction (XRD), conductivity, and environmental scanning electron microscopy (ESEM). On heating, the shorter ascorbyl alkanoates ( n ≤ 10) exhibit a coagel to micelle phase transition. By contrast the longer homologues ( n ≥ 11) exhibit a coagel to gel transition. The temperature, Δ H, and Δ S of the transitions depend on the length of the aliphatic side chain. The different phase behavior is related to the interplay of the competing molecular interactions that involve the hydrophobic chains of the amphiphiles, their headgroups, and the solvent.
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