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[2+3] Cycloaddition Reactions of Azido Metal Complexes and Crystal Structure of the Cycloadduct of (Ρh<sub>3</sub>Ρ)<sub>2</sub>Pd(Ν<sub>3</sub>)<sub>2</sub> with Benzonitrile
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1972
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Inorganic ChemistryChemical EngineeringCarbon DisulphideEngineeringHeterocyclicCrystal StructureCoordination ComplexOrganic ChemistryOrganic NitrilesOrganometallic CatalysisAzido Metal ComplexesChemistryInorganic Synthesis
Cycloaddition reactions of (R 3 P) 2 M(N 3 ) 2 (M = Pd, Pt) with organic nitriles, thiocyanates, isothiocyanates, dimethylacetylenedicarboxylate and carbon disulphide are described; an X-ray analysis of the crystal structure of bis (5-phenyltetrazolato) -bis (triphenylphosphine) palladium (II) is summarised and related to isomerism of the complex in solution.