Publication | Closed Access
Biomimetic Total Synthesis of Gambogin and Rate Acceleration of Pericyclic Reactions in Aqueous Media
90
Citations
55
References
2005
Year
EngineeringOrganic ChemistryChemistryRate AccelerationBiomimetic ChemistryChemical EngineeringSignificant Rate AccelerationCross-coupling ReactionTotal SynthesisFlow SynthesisSynthesis MethodNatural Product SynthesisEnantioselective SynthesisBiomolecular EngineeringBiomimetic Total SynthesisClaisen RearrangementPericyclic ReactionsReaction ProcessChemical Kinetics
A significant rate acceleration of a Claisen rearrangement and of a Claisen/Diels–Alder reaction cascade sequence was observed in the presence of water. This reaction sequence was used in a total synthesis of gambogin (1) from a tricyclic dialkene 3 via 2.
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