Concepedia

Thermal Decomposition of (NH<sub>4</sub>)<sub>2</sub>[Mo<sub>3</sub>S(S<sub>2</sub>)<sub>6</sub>] · nH<sub>2</sub>O

E. Diemann, Achim Müller, P. J. Aymonino

Zeitschrift für anorganische und allgemeine Chemie · 1981 · 51 citations · 6 references

DOI

Concepts

Abstract

Abstract The thermal decomposition of (NH 4 ) 2 [Mo 3 S(S 2 ) 6 ] · nH 2 O was studied by DTA/TG, infrared spectroscopy, X‐ray diffraction, determination of specific surfaces and temperature programmed desorption measurements. The results are reported and discussed with respect to the stability of the Mo IV ‐triangle system which is retained during the thermal treatment up to the formation of hexagonal MoS 2 , which can be understood nicely from a mechanistic point of view.

References

6

Preparation and Crystallinity of Molybdenum and Tungsten Sulfides

J. C. Wildervanck, F. Jellinek · Zeitschrift für anorganische und allgemeine Chemie · 1964 · 249 citations

, , +17

Eine einfache Darstellung der binären Metall‐Schwefel‐Cluster [Mo<sub>3</sub>S<sub>13</sub>]<sup>2−</sup> und [Mo<sub>2</sub>S<sub>12</sub>]<sup>2−</sup> aus MoO<sub>4</sub><sup>2−</sup> in praktisch quantitativer Ausbeute

Achim Müller, Ram Gopal Bhattacharyya, B. PFEFFERKORN · Chemische Berichte · 1979 · 115 citations

, , +12

Disulfur ligands in transition-metal coordination and cluster compounds

A. MUELLER, Wolfram Jaegermann · Inorganic Chemistry · 1979 · 74 citations

, , +15

Directed Synthesis of [Mo<sub>3</sub>S<sub>13</sub>]<sup>2−</sup>, an Isolated Cluster Containing Sulfur Atoms in Three Different States of Bonding

Achim Müller, Sabyasachi Sarkar, Ram Gopal Bhattacharyya et al. · Angewandte Chemie International Edition in English · 1978 · 74 citations

, , +15

Crystal Structure of (NH<sub>4</sub>)<sub>2</sub>[Mo<sub>3</sub>S(S<sub>2</sub>)<sub>6</sub>] Containing the Novel Isolated Cluster [MO<sub>3</sub>S<sub>13</sub>]<sup>2-</sup>

Achim Müller, S. POHL, M. DARTMANN et al. · Zeitschrift für Naturforschung B · 1979 · 65 citations · Full text

, , +14