Room-Temperature Palladium-CatalyzedAllyl Cross-Coupling Reaction with Boronic Acids Using Phosphine-FreeHydrazone Ligands

Takashi Mino, Kenji Kajiwara, Yoshiaki Shirae, Masami Sakamoto, Tsutomu Fujita

Synlett · 2008 · 45 citations · 0 references

Abstract

Palladium-catalyzed allyl cross-coupling reaction of allylic acetates with a variety of boronic acids at room temperature using a catalytic amount of Pd(OAc)2 with phosphine-free hydrazone as a ligand gave the allylbenzene derivatives in good yields.