Concepedia

Homogeneous Hydrogenations of Nitriles Catalyzed by Rhenium Complexes

K. Rajesh, B. Dudle, Olivier Blacque, Heinz Berke

Advanced Synthesis & Catalysis · 2011 · 77 citations · 36 references

DOI

Concepts

Abstract

Abstract Rhenium(I) nitrosyl complexes bearing large bite angle diphosphines efficiently catalyze the hydrogenation of nitriles to the corresponding symmetrical secondary amines.

References

36

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The analytical calculation of absorption in multifaceted crystals

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New Diphosphine Ligands Based on Heterocyclic Aromatics Inducing Very High Regioselectivity in Rhodium-Catalyzed Hydroformylation: Effect of the Bite Angle

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