Concepedia

On the breathing effect of a metal–organic framework upon CO2 adsorption: Monte Carlo compared to microcalorimetry experiments

Naseem A. Ramsahye, Guillaume Maurin, Sandrine Bourrelly, Philip L. Llewellyn, Thierry Loiseau, Christian Serre, Gérard Férey

Chemical Communications · 2007 · 154 citations · 20 references

DOI

Concepts

Abstract

Grand Canonical Monte Carlo simulations have explained the breathing of a metal-organic framework upon CO(2) adsorption, first suggested by microcalorimetry.

References

20

Reticular synthesis and the design of new materials

Omar M. Yaghi, M. O’Keeffe, N.W. Ockwig et al. · Nature · 2003 · 9K citations

, , +9

A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL‐53) Upon Hydration

Thierry Loiseau, Christian Serre, Clarisse Huguenard et al. · Chemistry - A European Journal · 2004 · 2.1K citations

, , +16

Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or Cr<sup>III</sup>(OH)·{O<sub>2</sub>C−C<sub>6</sub>H<sub>4</sub>−CO<sub>2</sub>}·{HO<sub>2</sub>C−C<sub>6</sub>H<sub>4</sub>−CO<sub>2</sub>H}<i><sub>x</sub></i>·H<sub>2</sub>O<i><sub>y</sub></i>

Christian Serre, Franck Millange, C. Thouvenot et al. · Journal of the American Chemical Society · 2002 · 1.9K citations

, , +12

Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks

Jesse L. C. Rowsell, Omar M. Yaghi · Journal of the American Chemical Society · 2006 · 1.8K citations

, , +17

Crystallized Frameworks with Giant Pores:  Are There Limits to the Possible?

Gérard Férey, Caroline Mellot‐Draznieks, Christian Serre et al. · Accounts of Chemical Research · 2005 · 1.3K citations

, , +17