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2D Chiral Uranyl(<scp>VI</scp>) Coordination Polymers with Second‐Harmonic Generation Response and Ferroelectric Properties
78
Citations
50
References
2003
Year
EngineeringInorganic PhotochemistrySynthetic PhotochemistryChemistryLuminescence PropertyInorganic MaterialPolymersLinear Chain CompoundChiral UranylUo 2Polymer ChemistrySecond‐harmonic Generation ResponseMaterials ScienceInorganic ChemistryPhotochemistryCoordination PolymersNo 3Situ Hydrothermal ReactionsPolymer ScienceCoordination PolymerMolecule-based MaterialFunctional Materials
Abstract The in situ hydrothermal reactions of UO 2 (NO 3 ) 2 with 1‐oxo‐4‐cyanopyridine (ocpy) and ethyl ( S )‐lactate (e‐la) afforded two unprecedented chiral 2D neutral luminescent square grids, uranyl‐bis(1‐oxo‐4‐pyridylcarboxylate) UO 2 (opyca) 2 ( 1 ) and homochiral uranyl‐bis[( S )‐lactate] ( 2 ). Their solid‐state structures, preliminary optical and photoluminescent properties are reported. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
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