Concepedia

Intermolecular Aerobic Oxidative Allylic Amination of Simple Alkenes with Diarylamines Catalyzed by the Pd(OCOCF<sub>3</sub>)<sub>2</sub>/NPMoV/O<sub>2</sub> System

Yosuke Shimizu, Yasushi Obora, Yasutaka Ishii

Organic Letters · 2010 · 91 citations · 28 references

DOI

Concepts

Abstract

Intermolecular aerobic oxidative allylic amination of simple alkyl alkenes with simple amines such as diphenylamine was induced by a Pd(OCOCF(3))(2)/NPMoV catalytic system, leading to the corresponding (E)-allylamines in good yield and selectivity through the formation of (eta(3)-allyl)palladium(II) trifluoroacetate species as a possible key intermediate.

References

28

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Mark S. Chen, M. Christina White · Journal of the American Chemical Society · 2004 · 514 citations

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<i>syn</i>-1,2-Amino Alcohols via Diastereoselective Allylic C−H Amination

Kenneth J. Fraunhoffer, M. Christina White · Journal of the American Chemical Society · 2007 · 340 citations · Full text

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Palladium‐Catalyzed Intermolecular Aerobic Oxidative Amination of Terminal Alkenes: Efficient Synthesis of Linear Allylamine Derivatives

Guosheng Liu, Guoyin Yin, Liang Wu · Angewandte Chemie International Edition · 2008 · 272 citations

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