Critical Review of Rate Constants for Reactions of Transients from Metal Ions and Metal Complexes in Aqueous Solution

Abstract

Kinetic data for transient metal species in aqueous solution have been critically reviewed. The compilation covers over 2000 measurements of rate constants involving 660 metal ions and metal complexes from Groups 4-15; lanthanides and actinides are not included. Most of the data have been obtained by the methods of pulse radiolysis or flash photolysis. Data have been collected from 500 publications through 1993.