Supramolecular Immobilization of a Perfluoro‐Tagged Pd‐Catalyst with Dendritic Architectures and Application in Suzuki Reactions

Abstract

Abstract A new supramolecular complex of a perfluoro‐tagged palladium phosphine catalyst to a dendritic core‐shell architecture with a perfluoroalkyl shell was used as recoverable catalyst for Suzuki couplings. This homogeneous complex can also serve as a model for related catalysts adsorbed on fluorous silica gel.