Physical Review Letters · 2001 · 277 citations · 10 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsMagnetic MaterialsPhase TransformationsAntiferromagnetismFerromagnetismMagnetic Properties Of SolidsMagnetism In SolidsPhase TransitionsSpin DynamicsDipolar InteractionsFinite-temperature MagnetismLong-range OrderLow-temperature MaterialsPhase Transition DynamicsSpontaneous Magnetization
It has recently been suggested that long-range magnetic dipolar interactions are responsible for spin ice behavior in the Ising pyrochlore magnets ${\mathrm{Dy}}_{2}{\mathrm{Ti}}_{2}{\mathrm{O}}_{7}$ and ${\mathrm{Ho}}_{2}{\mathrm{Ti}}_{2}{\mathrm{O}}_{7}$. We report here numerical results on the low temperature properties of the dipolar spin ice model, obtained via a new loop algorithm which greatly improves the dynamics at low temperature. We recover the previously reported missing entropy in this model, and find a first order transition to a long-range ordered phase with zero total magnetization at very low temperature. We discuss the relevance of these results to ${\mathrm{Dy}}_{2}{\mathrm{Ti}}_{2}{\mathrm{O}}_{7}$ and ${\mathrm{Ho}}_{2}{\mathrm{Ti}}_{2}{\mathrm{O}}_{7}$.
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Zero-point entropy in ‘spin ice’
A. P. Ramirez, A. Hayashi, R. J. Cava et al. · Nature · 1999 · 1.2K citations
The Nature of the Chemical Bond. V
Linus Pauling, G. W. Wheland · The Journal of Chemical Physics · 1934 · 249 citations
Natural Sciences, Chemistry, Physics +16