Angewandte Chemie International Edition in English · 1997 · 172 citations · 25 references
BiochemistryControversial MechanismRadical (Chemistry)Lipid PeroxidationRecent InvestigationsReaction IntermediateReaction ConditionsBiomolecular EngineeringJacobsen–katsuki Epoxidation
Radicals or manganaoxetanes–what are the intermediates in the Jacobsen–Katsuki epoxidation (see scheme on the right)? Recent investigations have shown that the mechanism of the epoxidation is strongly dependent on the substitutents of the alkene and on the reaction conditions.
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Catalytic asymmetric epoxidation of unfunctionalized olefins
Ryo Irie, Keiko Noda, Yoshio Ito et al. · Tetrahedron Letters · 1990 · 647 citations