A highly active palladium catalyst system for the arylation of anilines

New Diphosphine Ligands Based on Heterocyclic Aromatics Inducing Very High Regioselectivity in Rhodium-Catalyzed Hydroformylation: Effect of the Bite Angle

Mirko Kranenburg, Yuri E. M. van der Burgt, Paul C. J. Kamer et al. · Organometallics · 1995 · 841 citations · Full text

Bite Angle, Asymmetric Catalysis, Engineering +14

An Improved Catalyst System for Aromatic Carbon−Nitrogen Bond Formation:  The Possible Involvement of Bis(Phosphine) Palladium Complexes as Key Intermediates

John P. Wolfe, Seble Wagaw, Stephen L. Buchwald · Journal of the American Chemical Society · 1996 · 599 citations

Key Intermediates, Inorganic Chemistry, Chemical Engineering +14

A Second-Generation Catalyst for Aryl Halide Amination:  Mixed Secondary Amines from Aryl Halides and Primary Amines Catalyzed by (DPPF)PdCl₂

Michael S. Driver, John F. Hartwig · Journal of the American Chemical Society · 1996 · 475 citations

Cross-coupling Reaction, Mixed Secondary Amines, Engineering +12

Nickel-Catalyzed Amination of Aryl Chlorides

John P. Wolfe, Stephen L. Buchwald · Journal of the American Chemical Society · 1997 · 342 citations

An Ammonia Equivalent for the Palladium-Catalyzed Amination of Aryl Halides and Triflates

John P. Wolfe, Jens Åhman, Joseph P. Sadighi et al. · Tetrahedron Letters · 1997 · 335 citations

Halogenation, Aryl Halides, Chemical Engineering +8