Rational synthesis of anionic, neutral and cationic palladium(I) dinuclear complexes containing bridging conjugated dienes

Tetsuro Murahashi, Nobuko Kanehisa, Yasushi Kai, Toshiaki Otani, Hideo Kurosawa

Chemical Communications · 1996 · 34 citations · 8 references

Concepts

Abstract

Addition of conjugated diene to an equimolar mixture of palladium(II) halides and a palladium(0) complex induces facile Pd–Pd bond formation to give anionic, neutral and cationic PdI-PdI dinuclear complexes containing bridging 1,3-diene ligands.

References

8