Spin glass behaviour and extrinsic origin of magnetodielectric effect in non-multiferroic La₂NiMnO₆nanoparticles

Abstract

We report magnetization, dielectric and dc transport properties of La(2)NiMnO(6) nanoparticles. Both dc and ac magnetization measurements indicated a metastable magnetic behaviour with random ferromagnetic and antiferromagnetic interactions below 110 K; critical slow-down, memory and rejuvenation properties signify the spin glass nature. The dc resistivity shows a semiconducting nature but the temperature dependent magnetoresistance (MR) shows a peak at the spin glass transition. The colossal dielectric property and its frequency dependence were interpreted using the Maxwell-Wagner (MW) interfacial polarization model. Impedance analysis along with magnetodielectric (MD) and magnetoresistance (MR) indicates that the observed MD originates from the combined effect of MR and MW interfacial polarization.