Concepedia

ROMP-Spheres:  A Novel High-Loading Polymer Support Using Cross Metathesis between Vinyl Polystyrene and Norbornene Derivatives

Anthony G. M. Barrett, Susan M. Cramp, Richard S. Roberts

Organic Letters · 1999 · 83 citations · 14 references

DOI

Concepts

Abstract

The preparation of a polymer-supported ruthenium alkylidene metathesis catalyst is described. This immobilized catalyst has been used to initiate a ring-opening metathesis polymerization of norbornene derivatives onto a polymer support to prepare novel high-loading resins for use in combinatorial chemistry.

References

14

Recent advances in olefin metathesis and its application in organic synthesis

Robert H. Grubbs, Sukbok Chang · Tetrahedron · 1998 · 2.1K citations

, , +8

Synthesis and Applications of RuCl<sub>2</sub>(CHR‘)(PR<sub>3</sub>)<sub>2</sub>:  The Influence of the Alkylidene Moiety on Metathesis Activity

Peter Schwab, Robert H. Grubbs, Joseph W. Ziller · Journal of the American Chemical Society · 1996 · 2.1K citations

, , +16

Synthesis of molybdenum imido alkylidene complexes and some reactions involving acyclic olefins

Richard R. Schrock, John S. Murdzek, Gui C. Bazan et al. · Journal of the American Chemical Society · 1990 · 1.1K citations

, , +6

Ring-opening metathesis polymerization (ROMP) of norbornene by a Group VIII carbene complex in protic media

SonBinh T. Nguyen, Lynda K. Johnson, Robert H. Grubbs et al. · Journal of the American Chemical Society · 1992 · 989 citations

, , +11

Ring-Opening Metathesis Polymerization from Surfaces

Marcus Weck, J. J. Jackiw, Robert R. Rossi et al. · Journal of the American Chemical Society · 1999 · 268 citations

, , +11