Concepedia

Alkali‐Metal‐Mediated Manganation: A Method for Directly Attaching Manganese(II) Centers to Aromatic Frameworks

Joaquín García‐Álvarez, Alan R. Kennedy, J. Klett, Robert E. Mulvey

Angewandte Chemie International Edition · 2006 · 73 citations · 24 references

DOI

Concepts

Abstract

Magic Metalation: Inert towards conventional organomanganese reagents, ferrocene can now be directly manganated by using a specially designed mixed lithium/manganese(II) mixed dialkyl/amido reagent. The picture shows the structure of a dimanganese compound with three manganated 1,1′-ferrocenediyl fragments.

References

24

Modern Ate Chemistry:  Applications of Synergic Mixed Alkali-Metal−Magnesium or −Zinc Reagents in Synthesis and Structure Building

Robert E. Mulvey · Organometallics · 2006 · 344 citations

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The 2×3 Toolbox of Organometallic Methods for Regiochemically Exhaustive Functionalization

Manfred Schlosser · Angewandte Chemie International Edition · 2004 · 293 citations

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Regio- and Chemoselective Direct Generation of Functionalized Aromatic Aluminum Compounds Using Aluminum Ate Base

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Sodium Dialkyl-amidozincates:  Alkyl or Amido Bases? An Experimental and Theoretical Case Study

Prokopis C. Andrikopoulos, David R. Armstrong, H.R.L. Barley et al. · Journal of the American Chemical Society · 2005 · 141 citations

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Three-coordinate metal amides of manganese(II) and cobalt(II): synthesis and x-ray structure of the first tris(silylamide) of manganese and the x-ray crystal structures of [M2(N(SiMe3)2)4] (M = Mn, Co)

Brendan D. Murray, Philip P. Power · Inorganic Chemistry · 1984 · 139 citations

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