Concepedia

Vapor phase Beckmann rearrangement of cyclohexanone oxime over a novel tantalum pillared-ilerite

Younghee Ko, Myung Hun Kim, Sun Jin Kim, Young Sun Uh, Gon Seo, Miyoung Kim

Chemical Communications · 2000 · 39 citations · 6 references

DOI

Concepts

Abstract

The vapor phase Beckmann rearrangement of cyclohexanone oxime has been studied using a novel tantalum pillared-ilerite as catalyst: the cyclohexanone oxime conversion rate reaches 97.1% and the selectivity for ε-caprolactam is up to 89.1% at 350 °C.

References

6

Catalytically Active Sites for the Beckmann Rearrangement of Cyclohexanone Oxime to ε-Caprolactam

G. Heitmann, Gerd Dahlhoff, Wolfgang F. Hölderich · Journal of Catalysis · 1999 · 225 citations

, , +13

Beckman rearrangement of cyclohexanone-oxime on HNaY zeolites: kinetic and spectroscopic studies

A. Aucejo, M. Cruz Burguet, Avelino Corma et al. · Applied Catalysis · 1986 · 122 citations

, , +12

Vapor-phase beckmann rearrangement over alumina-supported boria catalyst prepared by vapor decomposition method

Satoshi Sato, Shin Hasebe, Hiroaki Sakurai et al. · Applied Catalysis · 1987 · 120 citations

, , +12

Vapor-Phase Beckmann Rearrangement over Silica-Supported Tantalum Oxide Catalysts

T. Ushikubo, Keisuke Wada · Journal of Catalysis · 1994 · 105 citations

, , +14

New route for synthesizing Mn-silicalite-1

Younghee Ko, Sun Jin Kim, Myung Hun Kim et al. · Microporous and Mesoporous Materials · 1999 · 42 citations

, , +12