Physical Review Letters · 1987 · 231 citations · 11 references
Natural SciencesMaterials EngineeringMaterials SciencePolymer ChemistryPolymer EngineeringSurface ScienceMembrane ElasticityMembrane MechanicsPhase TransitionsPolymer PhysicsPolymer SimulationPolymer SurfacesBending RigidityFinite-temperature EffectsFlexible Polymer ChainsLinear PolymersMechanics Of Curved MembranesMembrane Bending EnergyPolymer Surface SimulationSpecific Heat Capacity
The effect of a finite bending rigidity \ensuremath{\kappa}' on flexible, polymerized surfaces without self-avoidance is studied via the Monte Carlo method. Unlike linear polymers or liquid membranes, these surfaces undergo a remarkable finite-temperature crumpling transition, with a diverging specific heat. For small \ensuremath{\kappa}'/${\mathrm{k}}_{\mathrm{B}}$T, the surface is crumpled, and the radius of gyration ${\mathrm{R}}_{\mathrm{G}}$ grows as ln${\mathrm{L}}^{1/2}$, where L is the linear size of uncrumpled membrane. For large \ensuremath{\kappa}'/${\mathrm{k}}_{\mathrm{B}}$T, we find that the surface remains flat, i.e., ${\mathrm{R}}_{\mathrm{G}}$\ensuremath{\sim}L. Our results strongly suggest a finite-temperature crumpling transition in polymerized self-avoiding membranes as well.
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Scaling concepts in polymer physics
Strain fluctuations and elastic constants
Michele Parrinello, A. Rahman · The Journal of Chemical Physics · 1982 · 897 citations
A. Polyakov · Nuclear Physics B · 1986 · 721 citations