The Journal of Chemical Physics · 2012 · 93 citations · 34 references
Natural SciencesBiophysicsMolecular BiophysicsMolecular PhysicsPolymer ChemistryMolecular DynamicsPolymer ConformationPolymer Physical ChemistryPolymer PhysicsPolymer SimulationPolymer StructureChain Length DistributionLength EffectsMolecular Dynamics Of PolymersMolecular Dynamics Simulation Of Polymer ConformationNon-equilibrium RelaxationPolymer Chain DynamicsPolymer InteractionsPolymer-solvent Interactions
We study the dynamics of driven polymer translocation using both molecular dynamics (MD) simulations and a theoretical model based on the non-equilibrium tension propagation on the cis side subchain. We present theoretical and numerical evidence that the non-universal behavior observed in experiments and simulations are due to finite chain length effects that persist well beyond the relevant experimental and simulation regimes. In particular, we consider the influence of the pore-polymer interactions and show that they give a major contribution to the non-universal effects. In addition, we present comparisons between the theory and MD simulations for several quantities, showing extremely good agreement in the relevant parameter regimes. Finally, we discuss the potential limitations of the present theories.
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Brownian motion in a field of force and the diffusion model of chemical reactions
H. A. Kramers · Physica · 1940 · 8.6K citations
Natural Sciences, Chemistry, Physics +16
Fast DNA Translocation through a Solid-State Nanopore
A. J. Storm, Cornelis Storm, Jianghua Chen et al. · Nano Letters · 2005 · 731 citations · Full text
Polymer Translocation through a Pore in a Membrane
W. Sung, PooGyeon Park · Physical Review Letters · 1996 · 606 citations · Full text