The Physics of Fluids · 1966 · 321 citations · 27 references
Natural SciencesChemistryPhysicsPhysical ChemistryThermodynamicsTransport PhenomenaBoltzmann Transport EquationDiffusion ApproximationHeat ConductionTransport PropertiesAnalytic ApproximationsApproximation TheoryDiffusion CoefficientsGas MixturesGas Transport ModelingGas Transport PropertiesThermal ConductivityThermal Diffusion
Expressions are developed with the Chapman-Enskog-Burnett method for the third and fourth approximations to the thermal conductivity and the diffusion coefficients, and for the second approximation to the viscosity of multicomponent gas mixtures. Special forms of these expressions are then derived for application to ionized gas mixtures, in particular to the partially ionized gas. Convergence of the approximations is checked by computing the properties of fully ionized hydrogen and of several other mixtures where the molecules interact with inverse-power repulsive potentials. From the results for hydrogen, it is seen that at least the third approximation should be used for the thermal conductivity and thermal diffusion coefficient, and the second approximation for the electrical conductivity and viscosity of ionized gases. These results contrast with those for un-ionized gases where one lower level of approximation is generally adequate.
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<i>Molecular Theory of Gases and Liquids</i>
Joseph O. Hirschfelder, C. F. Curtiss, R. Byron Bird · Physics Today · 1955 · 11.4K citations
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A Viscosity Equation for Gas Mixtures
C. R. Wilke · The Journal of Chemical Physics · 1950 · 2.6K citations
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Transport Phenomena in a Completely Ionized Gas
Lyman Spitzer, Richard Härm · Physical Review · 1953 · 2.3K citations
Heat Conductivity of Polyatomic and Polar Gases
Edward A. Mason, L. Monchick · The Journal of Chemical Physics · 1962 · 576 citations
Natural Sciences, Chemistry, Physics +17