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New Three-Dimensional Metal−Organic Framework with Heterometallic [Fe−Ag] Building Units: Synthesis, Crystal Structure, and Functional Studies
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2011
Year
Materials ScienceInorganic ChemistryFunctional StudiesBig Window SizeSize SelectivityEngineeringCrystal StructureMetallic Functional MaterialOrganic ChemistryOrganometallic CatalysisCatalysisChemistryLewis Acid CatalysisMetal-organic PolyhedronMetal-organic FrameworksFunctional MaterialsInorganic SynthesisHybrid Materials
A new three-dimensional metal-organic framework (MOF) containing Fe(II) and Ag(I) ions and 2-pyrazinecarboxylic acid (pcaH) was synthesized, and its magnetic and catalytic properties were studied. The MOF has a big window size of 12.1 × 12.0 Å, with 23.8% solvent-accessible space, and shows size selectivity toward Lewis acid catalysis.