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Is coupled cluster singles and doubles (CCSD) more computationally intensive than quadratic configuration interaction (QCISD)?
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1989
Year
Ccsd EquationsEngineeringComputational ChemistryQuantum ComputingQuantum Optimization AlgorithmExcitation AmplitudesQci MethodQuadratic Configuration InteractionCluster SinglesQuantum ChromodynamicsQuantum SciencePhysicsQuantum Field TheoryQuantum AlgorithmNon-perturbative QcdQuantum ChemistryComputational ScienceNatural SciencesParticle Physics
It is shown that the recently proposed QCI method including all single and double substitutions has essentially the same computational requirements as the more complete CCSD approach. If properly formulated, the CCSD equations contain at most quadratic terms in the excitation amplitudes.
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