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Notable effect of imino substituent for the efficient ring-opening polymerization of ε-caprolactone initiated by Al complexes containing phenoxy-imine ligand of type, Me2Al(L) [L: O-2- Bu-6-(RN CH)C6H3; R: 2,6- Pr2C6H3, Bu, adamantyl, C6F5]

Rn ChEngineeringAl ComplexesImino SubstituentOrganic ChemistryChemistryBiomolecular EngineeringPolymer ReactionPolymer ChemistryPolymer SynthesisPolymers