Short-term in situ immobilization of Cd and Ni by beringite and steel shots application to long-term sludged plots

Abstract

Beringite and steel shots were mixed with the upper 20 cm of the soil. One year after addition, the extractabil- ity in calcium nitrate (0.1 M) and the plant availability of soil-Cd and -Ni were investigated. The addition of beringite (5 % w/w) and steel shots ( 1 % w/w) led to a lower extractability of Cd and Ni. In the most contaminated plots, the extractability of Cd and Ni after 1 year had decreased, respectively, 54 % and 53 % for beringite and 41 % and 40 % for steel shots. The metal content in different organs of maize plants (shoots, sixth leaf, ear leaf and grains), grown on the field trial, was determined. The Cd transfer from soil to plant decreased following the addition of beringite, except in the most contaminated plots. No decreased soil-plant transfer of Cd was observed after the addition of steel shots. Both the addition of beringite and steel shots led to a lower Ni transfer to the maize aerial organs and grains. No phytotoxicity or deficiency symptoms due to the additives were observed on the plants. The addition of beringite and steel shots seems promising to lower the soil-plant transfer of Ni at such metal contaminated soils. The depth of mixing and the method of application of the soil additives in the field appear to be very significant variables; additional comparative tests are needed, however. (@ Inra/Elsevier, Paris.) sewage sludge / cadmium / nickel / immobilization / soil-plant transfer Rsum -Immobilisation court-terme du Cd et du Ni in situ aprs l'apport de bringite et de grenaille d'acier dans des sols amends par des boues urbaines. La bringite et la grenaille d'acier ont t mlanges dans les 20 pre- miers cm d'un sol pollu par des mtaux. Un an aprs leurs apports, des extractions au nitrate de calcium (0,1 M) et la dtermination du transfert sol-mas pour le Cd et le Ni ont t ralises. L'addition de bringite (5% w/w) et de grenaille d'acier (1% w/w) ont diminu l'extractibilit du Cd et du Ni. Dans les parcelles les plus pollues, l'extractibilit de Cd Communicated by Marco Trevisan (Piacenza, Italy)