Advanced Materials · 2009 · 313 citations · 77 references
Natural SciencesMaterials SciencePhysicsInterface ScienceSolid State PhysicsThin FilmsInorganic MaterialsMagnetic OxidesMetal OxidesSuperconducting MaterialsSurface PhysicsThin Film Electrical PropertiesCation DisorderComplex OxidesInterface ReconstructionInterfacial Transport PropertiesMagnetic ScatteringOxide StructureOxygen VacanciesOxygen Vacancies In Metal Oxides
Abstract A large variety of transport properties have been observed at the interface between the insulating oxides SrTiO 3 and LaAlO 3 such as insulation, 2D interface metallicity, 3D bulk metallicity, magnetic scattering, and superconductivity. The relation between the structure and the properties of the SrTiO 3 /LaAlO 3 interface can be explained in a meaningful way by taking into account the relative contribution of three structural aspects: oxygen vacancies, structural deformations (including cation disorder), and electronic interface reconstruction. The emerging phase diagram is much richer than for related bulk oxides due to the occurrence of interface electronic reconstruction. The observation of this interface phenomenon is a display of recent advances in thin film deposition and characterization techniques, and provides an extension to the range of exceptional electronic properties of complex oxides.
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