Micellar, Liquid Crystalline and Polymer Systems Based on Surfactant and Polyethylene Imine as Nanoreactors for the Transfer of Phosphoryl Group

Dmitri Kudryavtsev, L. Ya. Zakharova, Ludmila Kudryavtseva, Al'Dona Raevska

Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals · 2001 · 10 citations · 8 references

Concepts

Abstract

Abstract In the kinetic study of the hydrolysis of p-nitrophenyl alkyl chloromethylphosphonates and p-nitrophenyl diphenyl phosphate in the cationic surfactant-polyethylene imine-water system the dependence of the catalytic effect of the system on the nature of surfactants and substrates and the surfactant-polyethylene imine ratio was found. An appearance of liotropic mesophase in the surfactant -polymer solutions results in alteration in the reactivity of the substrates.

References

8