Chemical Communications · 1998 · 65 citations · 6 references
Inorganic ChemistryChemical EngineeringEngineeringRhodium Trialkylphosphine ComplexesSupercritical Carbon DioxideTriethylphosphine ComplexesMuch Lower RatesOrganic ChemistryOrganometallic CatalysisCatalysisHomogeneous CatalysisChemistryMolecular CatalysisCatalytic SynthesisSupercritical Co2
Triethylphosphine complexes of rhodium catalyse the hydroformylation of hex-1-ene in supercritical carbon dioxide at rates similar to those obtained in toluene, but with a slightly improved n:i ratio; using trioctylphosphine, much lower rates are observed.
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Philip G. Jessop, Yi Hsiao, Takao Ikariya et al. · Journal of the American Chemical Society · 1996 · 605 citations