Concepedia

Assembly based on μ4-bridging thiolate: a new type of polymeric silver(I) complex having a one dimensional chain structure

Weipin Su, Rong Cao, Jiu‐Tong Chen, Jiaxi Lu

Chemical Communications · 1998 · 37 citations · 13 references

DOI

Concepts

Abstract

The polymeric silver(I)–thiolate complex [{Ag8(µ4-SC2H4- NH3)6Cl6}Cl2]n has been prepared from the assembling reaction of silver chloride and 2-mercaptoethylamine hydrochloride in DMF; X-ray diffraction analysis shows the complex has a one dimensional chain structure and all the sulfur atoms of the thiolates exhibit µ4 bonding bridging four silver(I) centers.

References

13

Thiolato-complexes of the transition metals

Philip J. Blower, Jonathan R. Dilworth · Coordination Chemistry Reviews · 1987 · 485 citations

, , +12

Transition‐Metal Thiolates: From Molecular Fragments of Sulfidic Solids to Models for Active Centers in Biomolecules

Bernt Krebs, Gerald Henkel · Angewandte Chemie International Edition in English · 1991 · 390 citations

, , +17

Two‐Dimensional Sheets of Tetragonal Copper(<scp>II</scp>) Lattices: X‐Ray Crystal Structure and Magnetic Properties of [Cu(C<sub>6</sub>O<sub>4</sub>Cl<sub>2</sub>)(C<sub>4</sub>H<sub>4</sub>N<sub>2</sub>)]<sub><i>n</i></sub>

Satoshi Kawata, Susumu Kitagawa, Mitsuru Kondo et al. · Angewandte Chemie International Edition in English · 1994 · 154 citations

, , +17

Supramolecular chemistry of manganese complex [Mn(CO)3(.mu.3-OH)]4: assembly of a cubic hydrogen-bonded diamondoid network with 1,2-diaminoethane

Steven B. Copp, S. Subramanian, Michael J. Zaworotko · Journal of the American Chemical Society · 1992 · 125 citations

, , +13

The intertwined double-(-AgSR-).infin.-strand chain structure of crystalline (3-methylpentane-3-thiolato) silver, in relation to (AgSr)8 molecules in solution

Ian Dance, Lyn J. Fitzpatrick, A. D. Rae et al. · Inorganic Chemistry · 1983 · 113 citations

, , +5