Concepedia

Convenient and direct preparation of tertiary phosphines via nickel-catalysed cross-coupling

Chemical Communications · 1997 · 97 citations · 10 references

Concepts

Natural SciencesChemistryCatalysisOrganic ChemistryCatalyst DesignCatalyst PreparationCross-coupling ReactionsHeterocycle SynthesisMetal CatalysisRedox CatalysisAryl Halide CouplingAsymmetric CatalysisAsymmetric Cross-couplingCross-coupling CatalysisNickel CatalysisNickel-catalyzed Cross-couplingStereoselective Cross-couplingTransition-metal-catalyzed Cross-coupling

Abstract

Nickel-catalysed cross-coupling of aryl sulfonates and aryl halides with chlorodiphenylphosphine and a reductant directly affords tertiary phosphines, which have application in a wide variety of asymmetric catalysis.

References

10

BINAP: an efficient chiral element for asymmetric catalysis

Ryōji Noyori, Hidemasa Takaya · Accounts of Chemical Research · 1990 · 1.3K citations

Natural Sciences, Biochemistry, Chemistry +8

Chiral Phosphinoaryldihydrooxazoles as Ligands in Asymmetric Catalysis: Pd‐Catalyzed Allylic Substitution

Peter Matt, Andreas Pfaltz · Angewandte Chemie International Edition in English · 1993 · 666 citations

Natural Sciences, Chemistry, Catalysis +13

Asymmetric synthesis. Production of optically active amino acids by catalytic hydrogenation

Michael D. Fryzuk, B. Bosnich · Journal of the American Chemical Society · 1977 · 545 citations

Natural Sciences, Biochemistry, Chemistry +11

Chiral Metal Complexes as Discriminating Molecular Catalysts

Ryōji Noyori · Science · 1990 · 270 citations

Natural Sciences, Chemical Engineering, Chemistry +14

Asymmetric synthesis. An asymmetric homogeneous hydrogenation catalyst which breeds its own chirality

Michael D. Fryzuk, B. Bosnich · Journal of the American Chemical Society · 1978 · 266 citations

Natural Sciences, Chemistry, Catalysis +11