Proceedings of the Physical Society · 1964 · 14 citations · 4 references
Natural SciencesChemistryPhysicsComputational ChemistryAb Initio MethodsApproximation MethodsBorn-oppenheimer ApproximationGround State Properties
A faulty discussion by Bopp in 1959 leading to an alleged lower bound for the energy of an N-electron system suggests a very simple approximate formula for the ground state energy. Calculations for the series of ions Be+, C2 +,... A8 + yield results with an accuracy to about 2%.
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Structure of Fermion Density Matrices
Alan Coleman · Reviews of Modern Physics · 1963 · 1.5K citations
J. C. Slater · Physical Review · 1929 · 1.3K citations