Organic Letters · 2013 · 15 citations · 24 references
Supramolecular AssemblyEngineeringPhotochemistryNatural SciencesPrecise Heteromeric OctamerMechanistic PhotochemistryMolecular BiologySynthetic PhotochemistryOrganic ChemistryPhotoresponsive Supramolecular G-quadruplexHexadecameric Supramolecular G-quadruplexChemistryPhotopolymer NetworkConstituent SubunitsSupramolecular PhotochemistryBiomolecular Engineering
Photoirradiation of a hexadecameric supramolecular G-quadruplex leads to a diastereoselective [2 + 2] cyclodimerization of half of its constituent subunits, which in turn shifts the equilibrium toward the formation of a precise heteromeric octamer.
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Self-Sorting: The Exception or the Rule?
An‐Xin Wu, Lyle Isaacs · Journal of the American Chemical Society · 2003 · 458 citations