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Furanosylidene and Iminofuranosylidene Complexes: Synthesis by Stoichiometric Olefin Metathesis and Ring-Opening/Mitsunobu-Recyclization Sequence

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References

1999

Year

Abstract

Transition metal activated furanosylidenes and iminofuranosylidenes are accessible by stoichiometric olefin metathesis and a ring-opening aminolysis/Mitsunobu recyclization sequence. The methodology has been applied to the synthesis of novel organometallic glycoconjugates (see picture).