Journal of Applied Physics · 2012 · 13 citations · 23 references
Natural SciencesMaterials SciencePhysicsMaterials ChemistryMaterials ThermodynamicsSolid-state ChemistryHigh-temperature MaterialsSelf-assembled MaterialsSelf-assembled NanostructuresSurface CrystallographySurface PhysicsThermodynamics Of NanomaterialsAnnealing Temperature EffectsAtomic CoordinationMultilayer AssemblyMultilayer StacksStructural StabilityTemperature StabilityTemperature-dependent StabilityThermal Stability Of Nanostructures
The effect of annealing on the structural stability of (Pt2nm/Co0.4 nm)3/IrMn7nm multilayers has been investigated using atom probe tomography. The composition of individual layers was measured after annealing at 300, 400, 500, and 700 °C. While results show that the (Pt/Co)3/IrMn stacking sequence is preserved up to 400 °C, there is an almost complete destruction of the multilayered structure when annealing at higher temperatures (500 and 700 °C). Co layers no more alternate with Pt-rich layers. The whole stack is transformed into an IrCo/PtMn bilayer. These results are interpreted on the basis of atomic mobilities and chemical affinities. Diffusion of Co and Mn is shown to become important when annealing temperature approaches 500 °C. Results are well accounted for by thermodynamics arguments considering the Co-Ir and Pt-Mn phase diagrams.
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