New convenient approach to the preparation of (Z)-allylic boronates via catalytic 1,4-hydroboration of 1,3-dienes with catecholborane

Catalytic Hydroboration with Rhodium Complexes

Detlef Männig, Heinrich Nöth · Angewandte Chemie International Edition in English · 1985 · 497 citations

Inorganic Chemistry, Chemical Engineering, Engineering +12

Asymmetric carbon-carbon bond formation via .beta.-allyldiisopinocampheylborane. Simple synthesis of secondary homoallylic alcohols with excellent enantiomeric purities

Herbert C. Brown, Prabhakar K. Jadhav · Journal of the American Chemical Society · 1983 · 486 citations

Bioorganic Chemistry, Engineering, Biochemistry +13

Diastereogenic Addition of Crotylmetal Compounds to Aldehydes

Reinhard W. Hoffmann · Angewandte Chemie International Edition in English · 1982 · 381 citations

Enantioselective Synthesis, Engineering, Natural Sciences +11

Enantiomeric Z- and E-crotyldiisopinocampheylboranes. Synthesis in high optical purity of all four possible stereoisomers of .beta.-methylhomoallyl alcohols

Herbert C. Brown, K. S. BHAT · Journal of the American Chemical Society · 1986 · 321 citations

Engineering, Donut Icon, .Beta.-methylhomoallyl Alcohols +13

Rhodium(I)-catalyzed hydroboration of olefins. The documentation of regio- and stereochemical control in cyclic and acyclic systems

David A. Evans, Gregory C. Fu, Amir H. Hoveyda · Journal of the American Chemical Society · 1988 · 198 citations

Chemical Engineering, Engineering, Alkene Metathesis +12