A chiral amidophosphine bearing a P–N bond and its π-allyl palladium(<scp>II</scp>) chemistry

Abstract

Camphor lactum phosphines 1 and 2, prepared from D-camphoric acid and D-camphor, respectively, act as bidentate P,O-ligands of palladium(II) where 1 is less hemilabile than 2, and in the dynamic behaviour of(π-allyl)palladium(II)complex 8 bearing 1, the bidentate coordination of this ligand is retained.